孙存发

联系方式

通讯地址：福建省厦门市集美区华侨大学材料科学与工程学院E4-308

实验室：华侨大学泛华科技大楼 B513

E-mail: Cunfa.SUN@hqu.edu.cn

教育及工作背景

2020 至今 华侨大学

2016.06 至 2020.01 能源材料化学协同创新中心，厦门大学,博士后/特聘助理研究员

2013.01 至 2016.02 都灵大学， 意大利,博士 

2009.09 至 2011.07 哈尔滨工业大学，哈尔滨,理学硕士

2005.09 至 2009.07 哈尔滨工业大学，哈尔滨,理学学士

研究方向

纳米团簇化学：

    纳米材料以其优异性能而得到广泛的研究和应用，其体相及表界面的组成和行为决定了其功能的多样性，由此材料的精确研究对其设计与合成具有指导性意义。纳米团簇材料的研究，填补了现有表征手段不足，使得纳米材料能够在分子尺度上进行精确地研究，并为材料的改善、设计及应用提供理论基础。

CO₂光/电催化:

    利用分子材料的研究，过渡到复杂的多相材料的设计、制备，并将其统一起来，对化学、材料科学的发展具有非常重要的意义。如在针对温室气体CO₂的催化还原基础研究中，分子材料、纳米材料、MOF等作为催化剂在光/电催化中得到了广泛的关注。通过设计不同金属有机化合物并对比其均相/异相电催化还原CO₂性能，为其他相关材料的设计提供了必要的依据。

稀土MOF材料:

    MOF材料由于其配体和金属的多样性而呈现出多样的性能，从设计合成到应用探索都得到了广泛的研究。其中稀土金属的特殊性能为MOF带来了更多的可能，如拓扑结构的研究、光/电/磁性能的开发应用、生物活性探索及催化材料的制备等。在分子层次上理解纳米材料及MOF材料的基础上，基于稀土金属的各种材料的设计、开发及应用有着更为广阔的前景。

发表论文：

Xin Ge a, Shuhuan Zeng a, Hongwen Deng b, Boon K. Teo b,* Cunfa Sun a,*Atom-precise copper nanoclusters based on FCC, BCC, and HCP structures, Coord.Chem. Rev., 503 (2024) 215667

Meng Wang,^‡ Simin Li,^‡ Huijun Chen,^‡ Xueli Sun, Jing Sun, Yanyuan Jia,* Shuo Guo, Cunfa Sun* and Hui Shen*, DppfCuBH₄: new reducing agents for the synthesis of ferrocene-functionalized metal nanoclusters, Dalton Trans., 2023, 52, 10332–10337

Shuhuan Zeng · Xin Ge · Hongwen Deng · Shuwei Hao · Zhiye Zhang · Boon K. Teo*· Cunfa Sun*, Synthesis and Structure of Polyhydrido Copper Nanocluster [Cu₁₄H₁₀(PPh₃)₈(SPhMe₂)₃]⁺: Symmetry-Breaking by Thiolate Ligands to form Racemic Pairs of Chiral Clusters in Solid-State, Journal of Cluster Science, doi:10.1007/s10876-023-02469-w

Sun, C., B. K. Teo, C. Deng, J. Lin, G.-G. Luo, C.-H. Tung, and D. Sun. 2021. Hydrido-coinage-metal clusters: Rational design, synthetic protocols and structural characteristics. Coord. Chem. Rev., 2021,  427.

Deng, C.#, C. Sun#, Z. Wang#, Y. Tao, Y. Chen, J. Lin, G. Luo*, B. Lin, D. Sun*, and L. Zheng.  A Sodalite-Type Silver Orthophosphate Cluster in a Globular Silver Nanocluster. Angew. Chem. Int. Ed., 2020, 59 (31):12659-12663.

Xiting Yuan, Cunfa Sun, Xihua Li, Sami Malola, Boon K Teo, Hannu Häkkinen,* Lan-Sun Zheng, Nanfeng Zheng*, Combinatorial Identification of Hydrides in a Ligated Ag40 Nanocluster with Non-compact Metal Core, J. Am. Chem. Soc., , 20219, 141 (30):11905-11911.. 

 Sun C.#, Mammen N.#, Kaappa S., Yuan P., Deng G., Zhao C., Yan J., Malola S., Honkala K., Hakkinen, H., Teo B. K., Zheng N., Atomically Precise, Thiolated Copper-Hydride Nanoclusters as Single-Site Hydrogenation Catalysts for Ketones in Mild Conditions, ACS Nano, 2019, 13, 5975-5986. 

 Yuan Peng#, Chen Ruihao#, Zhang Xiaomin, Chen Fengjiao, Yan Juanzhu, Sun Cunfa, Ou Daohui, Peng Jian, Lin Shuichao, Tang Zichao, Teo Boon K., Zheng Lan-Sun, Zheng Nanfeng. Ether-Soluble Cu53 Nanoclusters as an Effective Precursor of High-Quality CuI Films for Optoelectronic Applications, Angew. Chem. Int. Ed., 2019, 58, 835-839. 

Cunfa Sun, Laura Rotundo, Claudio Garino, Luca Nencini, Sam S. Yoon, Roberto Gobetto, and Carlo Nervi*, Electrochemical CO2 Reduction at Glassy Carbon Electrodes Functionalized by MnI and ReI Organometallic Complexes, ChemPhysChem, 2017,17, 3219-3229. 

C. Sun, R. Gobetto* and C. Nervi*, Recent Advances on Catalytic CO₂ Reduction by Organometal Complexes Anchored on Modified Electrodes, New J. Chem., 2016,40, 5656-5661. 

Cunfa Sun, Simona Prosperini, Pierluigi Quagliotto, Guido Viscardi, Sam S. Yoon, Roberto Gobetto and Carlo Nervi*, Electrocatalytic reduction of CO₂ by thiophene-substituted rhenium(I) complexes and by their polymerized films, Dalton Transactions, 2016,45, 14678-14688. 

Rui-Qing Fan*, Li-Yuan Wang, Ping Wang, Hong Chen, Cunfa Sun, Yu-Lin Yang, Qing Su. Syntheses, structures and luminescent properties of zero-/two-dimensional Cd(II) and Eu(III) complexes, Journal of Solid State Chemistry, 2012, 196, 332–340. 

Shuo Chen, Rui-Qing Fan*, Cunfa Sun, Ping Wang, Yu-Lin Yang, Qing Su, and Ying Mu. Synthesis, Structure and Luminescent Properties of Lanthanide-based 2D and 3D MOFs with 2,4′-Biphenyldicarboxylic Acid, Crystal Growth & Design, 2012, 12(3), 1337–1346.

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